ScintIQ™ Custom Scintillation Detectors — Data Sheet

CLYC:Ce Dual-Mode Scintillation Detectors

Cs₂LiYCl₆:Ce (CLYC) delivers simultaneous thermal-neutron and gamma detection in a single crystal, with pulse-shape discrimination that cleanly separates the two radiation types. Enriched to 96% Li-6, CLYC is the field-deployable dual-mode material of choice for nuclear identification instruments and advanced radiation portal monitors.

Density 3.31 g/cm³
Peak Emission 370 nm
Energy Resolution 4.5–5.5% FWHM @ 662 keV
Hygroscopic Yes

Doc type: Data Sheet  |  Revision 2, 2022-01-21  |  CLYC:Ce

CLYC:Ce scintillation crystal

1Overview

CLYC (Cerium-doped Caesium Lithium Yttrium Chloride, Cs₂LiYCl₆:Ce) is a halide scintillation crystal engineered for dual-mode radiation detection. A single CLYC detector simultaneously responds to thermal neutrons through Li-6 neutron capture and to gamma rays through normal Compton and photoelectric interactions. The two signal types are cleanly separated in the time domain using pulse-shape discrimination (PSD), making dedicated neutron-only or gamma-only detectors unnecessary in most fielded RIID systems.

What sets CLYC apart from other dual-mode materials is the combination of high Li-6 enrichment (96%), a relatively high light yield (approximately 20,000 photons/MeV), and decay components that support effective PSD. The gamma energy resolution of 4.5 to 5.5% FWHM at 662 keV is competitive with larger NaI(Tl) detectors, which is a meaningful advantage in nuclear identification instruments where source identification accuracy matters directly.

CLYC is hygroscopic and must be housed in a hermetically sealed detector assembly. Berkeley Nucleonics supplies CLYC fully packaged, matched to your readout preference. The thermal neutron peak appears at 3.1 to 3.3 MeV equivalent electron energy, well separated from the gamma continuum, which simplifies threshold-based discrimination even without full PSD processing.

For neutron-gamma applications requiring the highest resolution, see also the CLLBC:Ce data sheet, which trades some neutron cross-section for improved gamma resolution. For a deep treatment of PSD methods and figure-of-merit analysis, refer to the Neutron-Gamma Discrimination technical note.

2Specifications

Parameter Value Notes
Chemical formula Cs₂LiYCl₆:Ce Cerium-doped Caesium Lithium Yttrium Chloride
Crystal class Scintillation crystal (halide)
Density 3.31 g/cm³
Refractive index 1.81 (at 400 nm)
Wavelength of emission 275–450 nm Emission band
Peak emission wavelength 370 nm UV-visible range; well matched to bialkali PMTs
Decay time constants 1 ns, 50 ns, 1000 ns Three components; PSD exploits the difference between neutron and gamma decay profiles
Scintillation light yield approx. 20,000 photons/MeV
Li-6 enrichment 96% High enrichment maximizes thermal neutron cross-section
Melting point 640 °C
Hygroscopic Yes Hermetic sealed housing required
Pulse-shape discrimination Well possible Neutron/gamma separation confirmed; FOM depends on geometry and readout
Fast neutron detection Yes (via Cl-35) Neutron interaction with Cl-35 enables fast neutron response

3Energy Resolution and Performance

Parameter Value
Energy resolution at 662 keV (gamma) 4.5–5.5% FWHM (geometry-dependent)
Thermal neutron peak position 3.1–3.3 MeV (electron-equivalent)
Neutron/gamma discrimination Well possible via pulse-shape discrimination

The 4.5 to 5.5% range at 662 keV reflects genuine geometry dependence: smaller crystals often achieve the better end of that range. For comparison, NaI(Tl) typically delivers 7% at the same energy. The thermal neutron peak at 3.1 to 3.3 MeV equivalent sits well above the Cs-137 full-energy peak and Compton continuum, providing a wide separation window for software- or hardware-threshold discrimination.

CLYC pulse-shape discrimination or spectrum plot
CLYC:Ce scintillation response showing neutron and gamma signatures separated via pulse-shape discrimination. The thermal neutron peak at 3.1–3.3 MeV (electron-equivalent) is clearly resolved from the gamma continuum.
CLYC:Ce emission or resolution spectrum
CLYC:Ce emission spectrum. Peak emission at 370 nm is well matched to bialkali photomultiplier tubes and to silicon photomultipliers (SiPMs) with extended UV sensitivity.

The three-component decay structure (1 ns, 50 ns, 1000 ns) is key to PSD performance. Gamma interactions produce a different ratio of fast-to-slow components compared to neutron interactions, and modern pulse-shape analysis algorithms take advantage of this difference even in compact, low-power electronics. See the Neutron-Gamma Discrimination technical note for a detailed treatment of PSD figure of merit, thresholding, and implementation in portable RIID systems.

Fast neutron detection: Because of neutron interaction with Cl-35 in the crystal matrix, CLYC also responds to fast neutrons, extending its utility beyond pure thermal-neutron applications. Contact Berkeley Nucleonics to discuss fast-neutron configuration options.

4Typical Applications

  • Radioisotope identification devices (RIID): dual-mode neutron and gamma ID in a single portable instrument, meeting ANSI N42.34 and similar standards
  • Radiation portal monitors: high-throughput neutron/gamma screening at border crossings, ports, and checkpoints
  • Homeland security and threat detection: SNM (special nuclear material) detection where neutron sensitivity is required alongside gamma isotope ID
  • Nuclear safeguards and non-proliferation: field-deployable neutron/gamma coincidence measurements
  • Nuclear physics research: neutron spectroscopy, fast-neutron detection, coincidence experiments
  • Emergency response and decontamination surveys: simultaneous neutron and gamma mapping without detector changes
  • Active interrogation systems: induced fission signature detection requiring both radiation types

5Available Configurations

Berkeley Nucleonics supplies CLYC:Ce detectors as fully assembled, hermetically sealed packages. Crystal dimensions and readout options are configured to application requirements. The specifications below represent general capabilities; contact us with your dimensional and performance targets for a formal quotation.

Option Details
Crystal form Cylindrical or rectangular; custom dimensions (verify max dimensions with factory)
Housing Hermetically sealed aluminum or stainless steel (required; crystal is hygroscopic)
Readout: PMT Coupled to bialkali PMT optimized for 370 nm emission; standard voltage divider available
Readout: SiPM SiPM coupling available for compact, low-voltage, and high-magnetic-field environments (verify)
Window material UV-transmissive glass (standard); quartz available on request
Li-6 enrichment 96% standard (maximizes thermal neutron sensitivity)
Matched electronics Compatible with the ScintIQ bMCA, TOPAZ-HR, and bPAD readout modules

For the complete multi-crystal RIID detector configuration including housings, divider chains, and signal conditioning, see the V102AR406 PMT and Voltage Divider Assembly data sheet. For digital multi-channel analyzer readout, see the bMCA Ethernet data sheet.

6Request a Quote

Talk to a Berkeley Nucleonics Engineer

CLYC:Ce configurations are built to order. Share your crystal dimensions, readout preference, and performance targets and we will provide a formal quotation and lead-time estimate.

info@berkeleynucleonics.com   800-234-7858

You can also use the ScintIQ Detector Configurator to build a specification and submit a quote request online. For deeper background on neutron-gamma discrimination, pulse-shape discrimination techniques, and CLYC performance benchmarks, refer to the Neutron-Gamma Discrimination white paper.

ScintIQ crystals are grown and finished with our long-standing scintillation partner in the Netherlands (Scionix Holland).